Kind of interesting stuff, thought I'd share. Note that this applies to the base though, not the salt form that you'd get in a shard. But it's a combustible liquid? They even warn to avoid vapor accumulation so as to prevent explosions; I mean... seriously? :PMaterial Safety Data SheetVersion 3.3Revision Date 04/09/2013Print Date 05/10/2013COMPANY IDENTIFICATIONProduct name : N-IsopropylbenzylamineProduct Number : 136964Brand : AldrichSupplier : Sigma-Aldrich2. HAZARDS IDENTIFICATIONEmergency OverviewOSHA HazardsCombustible Liquid, IrritantGHS ClassificationFlammable liquids (Category 4)Skin irritation (Category 2)Eye irritation (Category 2A)Specific target organ toxicity - single exposure (Category 3)Acute aquatic toxicity (Category 3)GHS Label elements, including precautionary statementsPictogramSignal word WarningHazard statement(s)H227 Combustible liquidH315 Causes skin irritation.H319 Causes serious eye irritation.H335 May cause respiratory irritation.H402 Harmful to aquatic life.Precautionary statement(s)P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.HMIS ClassificationHealth hazard: 2Flammability: 2Physical hazards: 0NFPA RatingHealth hazard: 2Fire: 2Reactivity Hazard: 0Potential Health EffectsInhalation May be harmful if inhaled. Causes respiratory tract irritation.Skin May be harmful if absorbed through skin. Causes skin irritation.Eyes Causes eye irritation.Ingestion May be harmful if swallowed.3. COMPOSITION/INFORMATION ON INGREDIENTSSynonyms : N-BenzylisopropylamineFormula : C10H15NMolecular Weight : 149.23 g/molComponent ConcentrationN-Isopropylbenzylamine CAS-No.EC-No.102-97-6203-067-6-4. FIRST AID MEASURESGeneral advice Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.In case of skin contact Wash off with soap and plenty of water. Consult a physician.In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult aphysician.5. FIREFIGHTING MEASURESSuitable extinguishing media For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply waterfrom as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid streams of watermay be ineffective. Cool all affected containers with flooding quantities of water.Special protective equipment for firefighters Wear self contained breathing apparatus for fire fighting if necessary.Hazardous combustion products Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx)Further information Use water spray to cool unopened containers.6. ACCIDENTAL RELEASE MEASURES** Personal precautions Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove allsources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosiveconcentrations. Vapours can accumulate in low areas.Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environmentmust be avoided.Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place incontainer for disposal according to local regulations (see section 13). Keep in suitable, closed containers for disposal.7. HANDLING AND STORAGE** Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.** Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge.Conditions for safe storage Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealedand kept upright to prevent leakage.8. EXPOSURE CONTROLS/PERSONAL PROTECTION Contains no substances with occupational exposure limit values.Personal protective equipmentRespiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purposecombination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If therespirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and componentstested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).Hand protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touchingglove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use inaccordance with applicable laws and good laboratory practices. Wash and dry hands.Eye protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved underappropriate government standards such as NIOSH (US) or EN 166(EU).Skin and body protection impervious clothing, The type of protective equipment must be selected according to the concentration and amountof the dangerous substance at the specific workplace.Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end ofworkday.9. PHYSICAL AND CHEMICAL PROPERTIESAppearance Form clear, liquid Colour light yellowSafety data pH no data availableMelting point/freezing point no data availableBoiling point 200 C (392 F) - lit.Flash point 72 C (162 F) - closed cupIgnition temperature no data availableAuto-ignition temperature no data availableLower explosion limit no data availableUpper explosion limit no data availableVapour pressure no data availableDensity 0.892 g/cm3 at 25 C (77 F)Water solubility no data availablePartition coefficient: n-octanol/water no data availableRelative vapour density no data availableOdour no data available Odour Threshold no data availableEvapouration rate no data available10. STABILITY AND REACTIVITYChemical stability Stable under recommended storage conditions.Possibility of hazardous reactions no data availableConditions to avoid Heat, flames and sparks.Materials to avoid acids, Acid chlorides, Acid anhydrides, Strong oxidizing agents, Carbon dioxide (CO2)Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx)Other decomposition products - no data available11. TOXICOLOGICAL INFORMATIONAcute toxicityOral LD50 no data availableInhalation LC50Dermal LD50 no data availableOther information on acute toxicity no data availableSkin corrosion/irritation no data availableSerious eye damage/eye irritation no data availableRespiratory or skin sensitization no data availableGerm cell mutagenicity no data availableCarcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified asprobable, possible or confirmed human carcinogen by IARC.ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as acarcinogen or potential carcinogen by ACGIH.NTP: No component of this product present at levels greater than or equal to 0.1% is identified as aknown or anticipated carcinogen by NTP.OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as acarcinogen or potential carcinogen by OSHA.Reproductive toxicity no data availableTeratogenicity no data availableSpecific target organ toxicity - single exposure (Globally Harmonized System)Inhalation - May cause respiratory irritation.Specific target organ toxicity - repeated exposure (Globally Harmonized System) no data availableAspiration hazard no data availablePotential health effects** Inhalation May be harmful if inhaled. Causes respiratory tract irritation.** Ingestion May be harmful if swallowed.** Skin May be harmful if absorbed through skin. Causes skin irritation.** Eyes Causes eye irritation.** Signs and Symptoms of Exposure Cough, Shortness of breath, Headache, Nausea, Vomiting, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.Synergistic effects no data availableAdditional Information RTECS: Not available12. ECOLOGICAL INFORMATIONToxicity Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 38.5 mg/l - 48 hPersistence and degradability no data availableBioaccumulative potential no data availableMobility in soil no data availablePBT and vPvB assessment no data availableOther adverse effects An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.Harmful to aquatic life. no data available13. DISPOSAL CONSIDERATIONS Contact a licensed professional waste disposal service to dispose of this material. This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company.Contaminated packaging Dispose of as unused product.14. TRANSPORT INFORMATION DOT (US) NA-Number: 1993 Class: CBL Packing group: III** Proper shipping name: Combustible liquid, n.o.s. (N-Isopropylbenzylamine)Marine pollutant: No Poison Inhalation Hazard: NoIMDG Not dangerous goodsIATA Not dangerous goods15. REGULATORY INFORMATIONOSHA Hazards Combustible Liquid, IrritantSARA 302 Components No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.SARA 313 Components SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.SARA 311/312 Hazards Fire Hazard, Acute Health HazardMassachusetts Right To Know Components No components are subject to the Massachusetts Right to Know Act.Pennsylvania Right To Know Components N-IsopropylbenzylamineCAS-No.102-97-6New Jersey Right To Know Components N-IsopropylbenzylamineCAS-No.102-97-6California Prop. 65 Components This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.